IJSER Home >> Journal >> IJSER
International Journal of Scientific and Engineering Research
ISSN Online 2229-5518
ISSN Print: 2229-5518 5    
Website: http://www.ijser.org
scirp IJSER >> Volume 2, Issue 5, May 2011 Edition
Compost Adsorption Desdorption of Picloram in the Presence of Surfactant on Six Agricultural Soils
Full Text(PDF, 3000)  PP.  
Author(s)
Rounak M. Shariff
KEYWORDS
Adsorption - desorption kinetics, Adsorption isotherms, HPLC, Picloram, Surfactant.
ABSTRACT
To investigate the effect of different types of surfactants on adsorption behavior of pesticide, picloram [4-amino-3, 5, 6-trichloropicolinic acid] which is an ionic herbicide on six agricultural soil samples, picloram soil -water system-surfactant. The Freundlich adsorption coefficients Ks values for picloram adsorption in the presences of surfactant in three concentration of critical micelles concentration (cmc), batch equilibrium experiments performed of cationic surfactant Hexadecyltrimethylammonium bromide (HDTMA). The Ks values of picloram range between 0.940-1.344, 0.943-1.407, and 0.952-1.434 ml/g, for cmc/10, cmc and cmc*20 respectively. Freundlich adsorption coefficients of picloram in the presence of anionic surfactant sodium dodecyl sulphate (SDS) was determined, the values of Ks obtained were in the range 0.761-1.151, 0.654-1.141, and 0.631-1.099ml/g, for cmc/10, cmc, and cmc*20 respectively. The Ks values for polyoxyethylene sorbitanmonooleate ( tween-80) were in the range 0.971 -1.229, 1.104-1.303, and 1.189-1.404 ml/g, for cmc/10, cmc, and cmc*20 respectively. The values of Freundlich desorption coefficients (Ksdes), linearity factor for desorption (nsdes) and regression factor for desorption (R2) ranged from 0.839-1.286, 0.267-0.619, and 0.889-0.993 respectively with HDTMA. The values of Ksdes, nsdes and R2 values ranged from 0.895-1.289, 0.494-0.818, and 0.889-0.999 for desorption process respectively by anionic surfactant SDS, the values of Ksdes, nsdes and R2 ranged from 0.953-1.270, 0.429-0.650, and 0.888-0.995 respectively for non-ionic surfactant Tween-80.
References
[1] S.A. Wasay, W. Parker, P. J. Van Geel, S. Barrington and S. Tokunaga., ""Arsenic Pollution of a Loam soil: Retention from and Decontamination"". Journal of Soil Contamination. 9 (2000): 51- 64.

[2] Kahan, S. ""Equilibrium and Kinetic Studies of the Adsorption Studies of the Adsorption of 2, 4-D and Picloram on Humic Acid"". Canadian Journal of soil Science. 53 (1973):429-434.

[3] Nearpass, D.C. ""Adsorption of Picloram by Humic Acids and Humin"". Soil Sci. 121 (1976):272-277.

[4] Grover, R. ""Influence of Properties on Phytotoxicity of 4- Amino-3, 5, 6-Trichloropicolinic acid (Picloram)"". Weed Res. 8 (1968):226-232.

[5] Massaroppi, M.R.C.; Machado, S.A.S.; Avaca, .A. J. Braz. chem. Soc. 14 (2003):113.

[6] Tan L.K; Humphries D; Yeung PYp; Florence LZ. ""Determinations of Clopyralid, Picloram, and Silvex at Low Concentration in Soils by Calcium Hydroxide-Water Extraction and Gas Chromatography Measurement"". J. Agricult. Food Chem. 44 (1996):1135-1143.

[7] James W. Bigger, Uri Mingelgrin, and Max W. Cheung. ""Equilibrium and Kinetics of Adsorption of Picloram and Parathion with Soils"" J, Agric. Food Chem. 26( 1978):1306-1312

[8] M.S. Rodriguz-Cruz, M. J. Sanchez-Martin, and M. Sanchez- Camazano,. ""Enhanced Desorption of Herbicides Sorbed on Soils by Addition of TritonX-100"". J. Environ. Qual. 33 (2004):920-929.

[9] DiCesare, D., and J. A. Simth. ""Surfactant Effects on Desorption of Nonionic Compounds"". Rev. Environ. Contam. Toxicol.134 (1994):1-29.

[10] R.Celies, M. Real, M. C, Hermosin, and J. Crnejo, “Desorption, persistence, and leaching of dibenzofuran in European soils,” Soil Sci. Soc.Am. J. 70 (2006):1310-1317.

[11] R. Ahmad, R. S. Kookana, and A.M. Alston, Bulletin of Environ Contaminat and toxicol, 66 (2001):313-318.

[12] Rounak M. Shariff,” The Study of adsorption and desorption of Picloram on Six Agricultural Soils” Journal of Al-anbar un.iversity for Pure Scince, 3(2009):13-24.

[13] Aekseeva T., Besse P., Binet F. Delort A-M., Forano C., Sancelme M. ""Effect of Earthworms by Soil Ingestion on Atrazine Adsorption and Biodegradation” Applied and Environmental Microbiology"", 49 (2004):582-587.

[14] Piccolo, A. & Celano, G. ""Hydrogen-Bonding Interactions between the Herbicide Glyphosate and Water- Soluble Humic Substances"". Envirinmental Toxicology and Chemistry, 13 (1994):1737-1741.

[15] White, J.L., ""Clay-Particle Interactions"" In: Kaufman, D.D., Still, G.G., Paulson, G.D., Bandal, S.K. (Eds.), Bound and Conjugated pesticide Residues. ACS Symposium Series, Washington, (1976):208-218.

[16] Thanh H. Dao ""Competitive Anion Sorption Effects on Dairy West Water Dissolved phosphorus Extraction with Zeolitebased Sorbents"". Food, Agriculture & Environment., 4 (2003):263-269.

[17] Murphy, E. M. and Zachara, J.M. ""The Role of Sorbed Humic Substances on the Distribution of Organic and Inorganic Contaminants in Groundwater"", Geoderma. 67(1995): 103-124.

[18] Stearman, G.K., R.J. Ewis, L.J. Tortorelli, and D.D. Tyler. ""Herbicide Reactivity of Soil Organic Matter Fraction in No-Tilled Cotton"". Soil Sci. Am. J. 53 (1989): 1690-1694.

[19] Suman, G., Gajbhiye, v. T. ""Adsorption –Desorption, Presestance, and Leaching Beahavior of Dithiopyr in an Auuvial soil of India"". J. Environ. Sci. and Health. B 37(2002):573-586.

[20] Mohammed A Ali and Peter J. Baugh. ""Sorption, Desorption Studies of Six Pyerethroids and Mirex on Soils using GC/ MSNICI"" Internet. J. Environ. Anal. Chem., 83 (2003):923-933.

[21] Soledad M.; Andades R.; Sonia Rodri Guez-Cruz M.; Jesus Sanchez- Martin M., & Maria Sanchez-Camazano, January-March, ""Effect of the Modification of Natural Clay Minerals with Hexadecylpyridinium Cation on the Adsorption-Desorption of Fungicides"" Intern.J. Environ. Anal. Chem. 84 (2004):133-141.

[22] R. Ahmad., R. S. Kookona, A. M. Alston, and R. H. Bromilow, "" Difference in Sorption Behavior of Carbaryl and Phosalone in Soils from Australia"", Pakistan, and the United Kingdom. Aust. J. Soil Res., 39 (2001): 893-908.

[23] Baoshan Xing, Joseph J. Pingnatello, and Barbara Giglitti. ""Competitive Sorption between Atrazine and other Organic Compounds in Soils and Model Sorbents"". Environ. Sci. Technol. 30 (1996): 2432-2440

[24] Werkheiser, W.O. and Anderson, S.J. ""Effect of Soil Properties and Surfactant on Primisulfuron Sorption"". Journal of Environmental Quality, 25 (1996): 809-814.

[25] J. Park, S.D. Comfort, P. J. Shea, and T. A. Machacek. ""Remediating Munitions-Contaminated Soil with Zerovalent Iron and Cationic Surfactants"". J. Environ. Qual. 33 (2004): 1305-1313.

[26] Maria Jose Carrizosa, Pamela J. Rice, William C. Koskinen. Ignacio Carrizosa and Maria del Carmen Hermosin. Camazano. ""Sorption of Isoxaflutole and DKN on Organoclays"". Clay Minerals Socity. 52 (2004):341-349.

[27] Spalding, R.F., M.E. Exner, D.D. Snow, D.A. Cassada, M.E. Burbach, and S.J. Monson. ""Herbicides in ground water beneath Nebraska’s management systems evaluation area"". J. Environ. Qual. 32 (2003):92-99.

[28] Rosen, M.J. 1989. ""Sufactants and Interfacial Phenomena"". 2 nd Edition. John Wily and Sons. New York

[29] J. W. Bowden, A. M. Posner. And J. P. Quirk. ""Ionic Adsorption on Variable Charge Mineral Surfaces. Theoretical – Charge Development and Titration Curves"". Aust. J. Soi Res. l5 (1977): 121-124.

[30] M. Sanchez-camazano, M., M.J. Sanchej-Martin, M.S. Rodriguez- Curz. ""Sodium Dodycyl Sulphate-Enhanced Desorption of Atrazine: Effect of Surfactant Concentration and Organic Matter Content of Soil"". Chemosphere, 41 (2000):1310-1305.

[31] Rafael Celis and William C. Koskinen Aamaned. ""Characterization of Pesticide Desorption from Soil by the Isotopic Exchange Technique"" Soil Sci. Soc. Am. J. 63 (1999):1659-1666.

[32] Uan –Boh cheah, Ralph C. Kirkwood, Keng-Yeang Lum. ""Adsorption, Desorption and Mobility of four Commonly used Pesticides in Malaysian Agricultural soils"" Pesticide Science. 50 (1999):53-63.

[33] Locke, Martin A. Reddy, Krishan N., Gaston, lewis A., Zablotowicz, Robert. ""Adjuvant Modification of Herbicide Interactions in Aqueouse Soil Suspensions"" Soil Science. 2002. 167(7):444-452.

[34] Nelson, P. N., Baldock, A., Clarke, P., J. M., and Churchman, G. J. ""Dispersed Clay and Organic Matter in Soil: their Nature and Associations"". Australian Journal of Soil Research. 1999. 37: 289- 316.

[35] Mah Yew keong, K. Hidajat and M. S Uddin. ""Surfactant enhaned electro-Kinetic remedation of contaminated soil"". Journal of the Institution of Engineers, 45 (2005):61-70.

[36] Luning Pang and Murry Close. ""Afenuation and Transport of Atrazine and Picloram in an Alluvial gravel aquifer a Reacter Test and Batch Study"" New Zealandd Journal of Marine and Fresh Water Research. 333(1999):279-291.

[37] Ahmed F. El-Aswad. ""Effect of Organicamendments on Aldicarb Sorption-Desorption and Soil-Bound Residue"" Journal of Applied Sciences Research. 2007. 3(11) :1437-1448

[38] Zareen Khan, and Y.Anjaneyulu. ""Influence of Soil Components on Adsorption-Desorption of Hazardous Organics- Development of Low Cost Technology for Reclamation of Hazardous Waste Duumpsites"". Journal of Hazardous Materials. . 9 (2004):305-315.

[39] Liang k. Tan. David Humphries, Pauky, Y. P. Yeung and L.Zeak Fibo. ""Determinations of Clopyralid, Picloram, and Silvex at Low Concentration in Soils by Calcium Hydroxid Water Extraction and Gas Chromatography Measurment"". J. Agric. Food Chem. 44(1996):1135-1143.

[40] I. K. Konstantinon and T. A. Albanis. ""Adsorption- Desorption Studies of Selected Herbicides in Soil –Fly Ash Mixture"". J. Agrie. Food Chem. 48 (2000): 4780-4790.

[41] Davids. Kossen and Stephen V. Byrme. ""Interaction of Aniline with Soil and Ground Water at an Industrial Spill Site"". Environmental Health Preespective. . 103(1995):932-942.

Untitled Page